<?xml version="1.0" encoding="UTF-8"?>
<!DOCTYPE article PUBLIC "-//NLM//DTD Journal Publishing with OASIS Tables v3.0 20080202//EN" "journalpub-oasis3.dtd">
<article xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:oasis="http://docs.oasis-open.org/ns/oasis-exchange/table" dtd-version="3.0"><?xmltex \bartext{Science Reports}?>
  <front>
    <journal-meta>
<journal-id journal-id-type="publisher">SD</journal-id>
<journal-title-group>
<journal-title>Scientific Drilling</journal-title>
<abbrev-journal-title abbrev-type="publisher">SD</abbrev-journal-title>
<abbrev-journal-title abbrev-type="nlm-ta">Sci. Dril.</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1816-3459</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>

    <article-meta>
      <article-id pub-id-type="doi">10.5194/sd-20-13-2015</article-id><title-group><article-title>A key continental archive for the last 2 Ma of climatic
history of the central Mediterranean region: A pilot drilling in the Fucino Basin, central Italy</article-title>
      </title-group><?xmltex \runningtitle{A pilot drilling in the Fucino Basin, central Italy}?><?xmltex \runningauthor{B.~Giaccio et al.}?>
      <contrib-group>
        <contrib contrib-type="author" corresp="yes" rid="aff1">
          <name><surname>Giaccio</surname><given-names>B.</given-names></name>
          <email>biagio.giaccio@cnr.it</email>
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Regattieri</surname><given-names>E.</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff2">
          <name><surname>Zanchetta</surname><given-names>G.</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-7080-9599</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff3">
          <name><surname>Wagner</surname><given-names>B.</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1 aff4">
          <name><surname>Galli</surname><given-names>P.</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff2">
          <name><surname>Mannella</surname><given-names>G.</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff5">
          <name><surname>Niespolo</surname><given-names>E.</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Peronace</surname><given-names>E.</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff5 aff6">
          <name><surname>Renne</surname><given-names>P. R.</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff7">
          <name><surname>Nomade</surname><given-names>S.</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Cavinato</surname><given-names>G. P.</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Messina</surname><given-names>P.</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Sposato</surname><given-names>A.</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff8">
          <name><surname>Boschi</surname><given-names>C.</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff9">
          <name><surname>Florindo</surname><given-names>F.</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-6058-9748</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff9">
          <name><surname>Marra</surname><given-names>F.</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff10">
          <name><surname>Sadori</surname><given-names>L.</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-2774-6705</ext-link></contrib>
        <aff id="aff1"><label>1</label><institution>Istituto di Geologia Ambientale e Geoingegneria, CNR, Rome, Italy</institution>
        </aff>
        <aff id="aff2"><label>2</label><institution>Dipartimento di Scienze della Terra, UniPI, Pisa, Italy</institution>
        </aff>
        <aff id="aff3"><label>3</label><institution>Institute of Geology and Mineralogy, University of Cologne, Cologne,
Germany</institution>
        </aff>
        <aff id="aff4"><label>4</label><institution>Dipartimento di Protezione Civile Nazionale, Rome, Italy</institution>
        </aff>
        <aff id="aff5"><label>5</label><institution>Department of Earth and Planetary Science, University of California,
Berkeley, USA</institution>
        </aff>
        <aff id="aff6"><label>6</label><institution>Berkeley Geochronology Center, Berkeley, USA</institution>
        </aff>
        <aff id="aff7"><label>7</label><institution>Laboratoire des Sciences du Climat et de l'Environnement
(CEA-CNRS-UVSQ), Gif-Sur-Yvette, France</institution>
        </aff>
        <aff id="aff8"><label>8</label><institution>Istituto di Geoscienze e Georisorse, CNR, Pisa, Italy</institution>
        </aff>
        <aff id="aff9"><label>9</label><institution>Istituto Nazionale di Geofisica Vulcanologia, Rome, Italy</institution>
        </aff>
        <aff id="aff10"><label>10</label><institution>Dipartimento di Biologia Ambientale, University of Rome “La
Sapienza”, Rome, Italy</institution>
        </aff>
      </contrib-group>
      <author-notes><corresp id="corr1">B. Giaccio (biagio.giaccio@cnr.it)</corresp></author-notes><pub-date><day>17</day><month>December</month><year>2015</year></pub-date>
      
      <volume>20</volume>
      <issue>20</issue>
      <fpage>13</fpage><lpage>19</lpage>
      <history>
        <date date-type="received"><day>9</day><month>September</month><year>2015</year></date>
           <date date-type="rev-recd"><day>10</day><month>November</month><year>2015</year></date>
           <date date-type="accepted"><day>15</day><month>November</month><year>2015</year></date>
      </history>
      <permissions>
<license license-type="open-access">
<license-p>This work is licensed under a Creative Commons Attribution 3.0 Unported License. To view a copy of this license, visit <ext-link ext-link-type="uri" xlink:href="http://creativecommons.org/licenses/by/3.0/">http://creativecommons.org/licenses/by/3.0/</ext-link></license-p>
</license>
</permissions><self-uri xlink:href="https://sd.copernicus.org/articles/20/13/2015/sd-20-13-2015.html">This article is available from https://sd.copernicus.org/articles/20/13/2015/sd-20-13-2015.html</self-uri>
<self-uri xlink:href="https://sd.copernicus.org/articles/20/13/2015/sd-20-13-2015.pdf">The full text article is available as a PDF file from https://sd.copernicus.org/articles/20/13/2015/sd-20-13-2015.pdf</self-uri>


      <abstract>
    <p>An 82 m long sedimentary succession was retrieved from the Fucino Basin, the
largest intermountain tectonic depression of the central Apennines. The basin
hosts a succession of fine-grained lacustrine sediments (ca. 900 m-thick)
possibly continuously spanning the last 2 Ma. A preliminary
tephrostratigraphy study allows us to ascribe the drilled 82 m long record
to the last 180 ka. Multi-proxy geochemical analyses (XRF scanning, total
organic/inorganic carbon, nitrogen and sulfur, oxygen isotopes) reveal
noticeable variations, which are interpreted as paleohydrological and
paleoenvironmental expressions related to classical glacial–interglacial
cycles from the marine isotope stage (MIS) 6 to present day. In light of the
preliminary results, the Fucino sedimentary succession is likely to provide
a long, continuous, sensitive, and independently dated paleoclimatic archive
of the central Mediterranean area.</p>
  </abstract>
    </article-meta>
  </front>
<body>
      

      <?xmltex \floatpos{t}?><fig id="Ch1.F1" specific-use="star"><caption><p>Reference map of the Fucino Plain with a representative seismic
line. <bold>(a)</bold> Shaded relief of the Fucino Plain showing the location of the
GeoLazio (GL), Telespazio (TS), Strada Provinciale 20 (SP) and Fucino 1 and
3 (F1–3; this study) boreholes. Dashed blue lines are the isochrones (in ms)
of the Plio–Quaternary basin infilling with respect to the Quaternary master
faults (red bold lines) responsible for the asymmetrical (half-graben) basin
geometry. Dotted green lines are the traces of the available seismic lines.
<bold>(b)</bold> Seismic line 3 (see trace in panel <bold>a</bold>) showing the internal architecture
of the Plio–Quaternary continental deposits of the Fucino Basin along a
W–E-oriented profile. The projected location of the GL, SP, and F1–3
boreholes is also shown. A, B, C: main unconformities; Seq. 2: Messinian
foredeep sediments; Seq. 3: Pliocene fluvial and alluvial deposits; Seq. 4:
Quaternary lacustrine and fluvial deposits. The figure and the information were compiled
with some modifications from Cavinato et al. (2002), Galli et al. (2012),
and Patacca et al. (2008).</p></caption>
      <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://sd.copernicus.org/articles/20/13/2015/sd-20-13-2015-f01.jpg"/>

    </fig>

<sec id="Ch1.S1" sec-type="intro">
  <title>Introduction</title>
      <p>Understanding the spatio-temporal variability, the magnitude, and the
different expressions of Quaternary orbital and millennial-scale
paleoclimatic changes across regions is a frontier challenge of modern
paleoclimatology (e.g. EPICA community members, 2006). Addressing this issue
requires the acquisition of regionally representative high-resolution and
well-dated records of climatic variability.</p>
      <p>In this framework, the Fucino paleolake in central Italy (Fig. 1a) should
add a nodal point in the western, currently vacant area of a network of long
terrestrial Mediterranean records (including e.g. the Dead Sea (Neugebauer et
al., 2014), Lake Van (Litt and Anselmetti, 2014), Lake Ohrid (Wagner et al.,
2009), and  the Tenaghi Philippon (Pross et al., 2015)). Indeed, among the central
Italy intermountain tectonic depressions, it is probably one of the oldest
and the only one that hosts a continuous, lacustrine succession since the
late Plio–Quaternary (Fig. 1b). The site is also ideal because of its
proximity to Quaternary peri-Tyrrhenian volcanic centres (Fig. 2) that on
occasion deposited tephras in the basin that serve today as important
chronological marker beds (e.g. Giaccio et al., 2012, 2015; Regattieri et
al., 2015). This is a crucial requirement for comparing intra- and
inter-regional paleoclimatic records, based on different dating methods, for
evaluating the temporal relationship between them and with respect to the
main climatic forcing (e.g. orbital).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F2"><caption><p>Location of the Fucino Basin with respect to the main volcanic
districts of  central and southern Italy (age in brackets represent the
interval of volcanic activity). It is in a good range of distance with
respect to the Quaternary tephra sources and in a favourable position with respect to the
prevailing eastward direction of the stratospheric winds and hence for
tephra dispersion. The locations of   Sulmona and Campo Felice are
also shown.</p></caption>
        <?xmltex \igopts{width=236.157874pt}?><graphic xlink:href="https://sd.copernicus.org/articles/20/13/2015/sd-20-13-2015-f02.png"/>

      </fig>

      <p>With this purpose, an 82 m long core was recovered from the central eastern
Fucino Basin (F1–3 in Fig. 1) in June 2015. The major goals of this drilling
were to  (i) collect a continuous record back to MIS (marine isotope stage) 6, (ii) assess the
quality of the lacustrine sedimentary succession, (ii) explore the
sensitivity of different paleoclimatic proxies, and (iii) document the
presence of widespread tephras useful for regional to extra-regional
correlation and their suitability for <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mn>40</mml:mn></mml:msup></mml:math></inline-formula>Ar/<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mn>39</mml:mn></mml:msup></mml:math></inline-formula>Ar dating.</p>
</sec>
<sec id="Ch1.S2">
  <title>Geological setting and general background</title>
      <p>The Fucino Basin (Fig. 1) is one of the largest intermountain depressions
formed during the Plio–Quaternary extensional phase along the Apennine Chain
(e.g. D'Agostino et al., 2001) within the earlier fold-and-thrust-belt
system (e.g. Patacca and Scandone, 2007). Its opening was mainly driven by a
major 110–130<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N trending fault system (Galadini and
Galli, 2000; Fig. 1a), which led to the formation of a typical half graben
with up to <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 900 m of thick Quaternary deposits in the
hanging wall of the master faults (Cavinato et al., 2002; Fig. 1b). Prior to
the drainage, undertaken first by Romans in 1st century AD and then at
the end of the 19th century (e.g. Galadini and Galli, 2001), the Fucino
Basin hosted the largest lake (<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 150 km<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula>, 20 m maximum
water depth) of peninsular Italy.</p>
      <p>In the past decades, several cores were drilled in the Fucino Basin for scientific and
geotechnical purposes (Fig. 1). A preliminary
palynological study of the 200 m long GeoLazio core (GL in Fig. 1) led to
the conclusion that the upper 65 m of the succession would span the last
130 ka
(Follieri et al., 1986). However, the dating of a thick tephra layer at
<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 101 m depth yielded an age of 540 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 9 ka (Follieri et
al., 1991), hardly compatible with this chronological framework. Later,
Narcisi (1994) analysed two foiditic tephra occurring in the GeoLazio and
Telespazio cores (TS in Fig. 1), at <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 12–14 m depth, which, on
the basis of their peculiar glass major element composition, were attributed
to the eruptive units Albano 5–7 (Giaccio et al., 2007), from a cluster of
Colli Albani eruptions dated between 40 and 36 ka (Giaccio et al., 2009).
Finally, the tephrostratigraphic study of a 30 m deep borehole (SP in Fig. 1a)
drilled close to the GeoLazio site, and in a comparable range of the
isochrones of the Quaternary infill (Fig. 1a), allowed for the recognition of
some relevant tephra markers spanning between ca. 18 and ca. 160 ka
(Authors' unpublished data; Fig. 3). All of these chronological constraints
lead us to a  reinterpretation of the chronology of the GeoLazio pollen
record, spanning the MIS 1–9 interval, suggesting that the Fucino
succession extends continuously at least back to <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 540 ka
(Fig. 3).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F3"><caption><p>Revised depth–age curve for the GeoLazio arboreal pollen (AP)
profile (Follieri et al., 1986) based on the recognition of marker tephra
layers in core SP (Fig. 1) and on the dating of the layer at <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 101 m
of depth in core GeoLazio (Follieri et al., 1991). After revision, the
resulting AP curve shows a variability, which correlates quite well the
benthic <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O stack (Lisiecki and Raymo, 2005) from MIS 9 to
today.</p></caption>
        <?xmltex \igopts{width=241.848425pt}?><graphic xlink:href="https://sd.copernicus.org/articles/20/13/2015/sd-20-13-2015-f03.png"/>

      </fig>

</sec>
<sec id="Ch1.S3">
  <title>Material and methods</title>
<sec id="Ch1.S3.SS1">
  <title>Drilling site selection and procedure </title>
      <p>The drilling site was selected using an evaluation of sedimentation rate
obtained from the new interpretation of the GeoLazio pollen profile (Fig. 3)
and the general sedimentary–tectonic architecture of the basin (Fig. 1).
With the aim to recover a record spanning back into MIS 6, we selected an
area located some kilometres eastward from the GeoLazio and SP core sites, i.e.
toward the depocentre where the isochrones are deeper (Fig. 1). Therefore, this site
provided  us the opportunity of recovering a succession more expanded than
the GeoLazio core.</p>
      <p>At the selected site (42.00<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, 13.56<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> E), two
parallel cores were recovered. The first hole (F1) was drilled down to a
field depth of 75 m and the second hole (F3) down to 56.25 m. The length of
the single recovered core section was 1.5 m, with an overlap of 75 cm
between the two holes, in order to obtain a complete sedimentary succession
for the upper part of the sequence. Samples from core catchers were taken
directly in the field, whereas the rest of the cores were stored in a dark
and cool place for further analyses.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F4" specific-use="star"><caption><p>Provisional tephrochronological framework of the Fucino F1–3
composite stratigraphy. The provisional correlation of some of the F1–F3
tephras – which are also depicted by peaks in K, Rb, and Sr – has been
tentatively established on their stratigraphic order and lithological
features compared to the tephra successions from the local cores of Fucino
SP and the chronologically recalibrated GeoLazio and cores from the
surrounding basins of Campo Felice (Giraudi and Giaccio, 2015) and Sulmona
(Giaccio et al., 2012; Regattieri et al., 2015) (Fig. 2).</p></caption>
          <?xmltex \igopts{width=369.885827pt}?><graphic xlink:href="https://sd.copernicus.org/articles/20/13/2015/sd-20-13-2015-f04.png"/>

        </fig>

</sec>
<sec id="Ch1.S3.SS2">
  <title>Laboratory work</title>
<sec id="Ch1.S3.SS2.SSS1">
  <title>Lithological analyses and XRF scanning</title>
      <p>Core opening and core description was carried out at the laboratory of the
University of Cologne, Germany. Immediately after core opening, a surface
scan of each core section was carried out with a line scan camera from an
Itrax core scanner (Cox, Sweden). Further analyses included XRF (X-ray fluorescence) scanning
carried out with a chromium (Cr) X-ray source at 30 kV and 55 mA at 2.5 mm
resolution and 10 s integration time.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F5"><caption><p>Proxy series plotted on preliminary composited depth. From bottom,
provisional age control points based on the supposed recognition of the
tephra layers as shown in Fig. 4: <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">TIC</mml:mi></mml:msub></mml:math></inline-formula>, total
inorganic carbon (TIC %), total organic carbon (TOC %), TOC <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> TN ratio,
total sulfur (TS %) (all from the same core catcher samples), and Ti and Ca
from XRF scanning; thick lines are 20 pt  running averages, note that the Ti
scale is reversed. Blue/pink shadowing indicates marine isotope stages (MIS)
following the correlation proposed in Fig. 4. The provisional sub-stage
subdivision of the MIS 5 is also shown.</p></caption>
            <?xmltex \igopts{width=236.157874pt}?><graphic xlink:href="https://sd.copernicus.org/articles/20/13/2015/sd-20-13-2015-f05.jpg"/>

          </fig>

</sec>
<sec id="Ch1.S3.SS2.SSS2">
  <title>Geochemical analyses on core catcher material</title>
      <p>Total carbon (TC), total inorganic carbon (TIC), total nitrogen (TN), total
sulfur (TS), and stable oxygen isotope compositions  were carried out on
discrete samples from the top of each core catcher. Samples were dried in an
oven at 50 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C. After disaggregation and sieving, the fraction
below 100 <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula> was powdered and homogenized for geochemical analyses.</p>
      <p>Stable isotope analyses were performed on samples with &gt; 20 %
carbonate content using a GasBench II (Thermo Scientific) coupled to a
Delta XP IRMS (Finnigan) at the Institute of Geosciences and Earth Resources
of the Italian National Research Council (IGG-CNR) of Pisa (Italy).
Carbonate samples of <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 0.15 mg of total CaCO<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula> were
dissolved in H<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula>PO<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">4</mml:mn></mml:msub></mml:math></inline-formula> (100 %) for 1 h at 70 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C. All
the results are reported relative to the V-PDB (Vienna Pee Dee Belemnite) international standard and
corrected using the international standards NBS-18 (National Bureau of Standards) and a set of three internal
standards. The analytical uncertainties for <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O and <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>13</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>C are 0.17 and 0.15 ‰
respectively. TN and TS were determined with a vario Micro cube combustion
CNS elemental analyser (Elementar, Germany) after combustion at 1150 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C
at the University of Cologne, Germany. TC and TIC were measured with a
DIMATOC 200 (DIMATEC, Germany) at the University of
Cologne, Germany.  TOC  was calculated by subtracting TIC from TC.</p>
</sec>
</sec>
</sec>
<sec id="Ch1.S4">
  <title>First results and preliminary discussion</title>
      <p>Both cores are composed of grey lacustrine calcareous marl, with a variable
proportion of clay. A preliminary 82 m long composite succession is based on
visual correlation after core opening and using the line scan images from
the Itrax core scanner (Cox Analytical, Sweden) and the Corewall software
package (Corelyzer 2.0.1). Core sections that looked disturbed from the
coring process were not included in the core composite. Although,
theoretically, the drilling depths should have avoided gaps between the
individual runs in each hole, overlapping sequences in the lower part of the
F3 hole indicated gaps of around 20 cm between the individual runs of the F1
hole due to core expansion after recovery. We therefore assumed 20 cm gaps
between the F1 sequences, where there were no overlapping F3 sequences;
i.e. for the depths &gt; <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 55 m. Based on the core
composite stratigraphy, Ca, K, Ti, Rb, and Sr data from XRF scanning were
compiled to produce an overview profile.</p>
      <p>At least 16  centimetric to decimetric
thick and relatively coarse-grained tephra layers
were identified along the composite core, several of which are also clearly
marked by prominent spikes in K, Rb, and Sr (Fig. 4). A provisional
correlation of some of the tephras has been tentatively established based on
their stratigraphic order and lithological features (e.g. overall tephra
colour, thickness, grain size, assortment of the mineral and lithic
components, and colour and shape of the juvenile clasts) compared to the local
tephra successions from the Fucino core SP and the chronologically
recalibrated GeoLazio core (Fig. 3) and cores from the surrounding basins of
Campo Felice (Giraudi and Giaccio, 2015) and Sulmona (Giaccio et al., 2012;
Regattieri et al., 2015) (Figs. 3, 4). Although the lack of robust
geochemical data renders it premature to propose an age model based on
tephrochronology alone, general tephrostratigraphic consistency allows us to
ascribe the investigated successions to the MIS 6–1 period. The
resulting sedimentation rate would range between <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 0.3 and 0.6 mm a<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>,
with a mean of <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 0.45 mm a<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>, which is substantially
higher than that of the GeoLazio/SP succession (<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 0.2 mm a<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>;
Fig. 3).</p>
      <p>Geochemical and biogeochemical analyses from core catcher material show
significant variability, with major trends consistent between the different
proxies and with XRF data for Ca and Ti (Fig. 5). There is a strong
(<inline-formula><mml:math display="inline"><mml:mrow><mml:mi>r</mml:mi><mml:mo>=</mml:mo><mml:mn>0.95</mml:mn></mml:mrow></mml:math></inline-formula>) negative correlation between Ca and Ti. Due to this strong
anticorrelation and to the fact that Ca and TIC depth series show nearly
identical patterns of variation, we assume that both proxies are mainly
related by authigenic (i.e. biomediated) precipitation of calcite. The
amount of calcite in the sediments depends on lake primary productivity,
temperature, the input of Ca from the catchment (e.g. Gierlowsky-Kordesh,
2010; Vogel et al., 2010), and the preservation of calcite as a function of
organic matter (OM) decomposition and bacterial CO<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula> release in the
bottom waters (e.g. Müller et al., 2006). Also, TOC is mainly a function
of changes in organic production in the lake and of changes in catchment
vegetation (Leng et al., 2013), and, along with TIC, it tends to be higher
during warmer and wetter periods (i.e. interglacials/interstadials).
During these periods, calcite (TIC <inline-formula><mml:math display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 8.33) and organic matter (TOC <inline-formula><mml:math display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 2.5)
derived from TIC and TOC may form up to
&gt; 90% of the total sediments (Fig. 5). This suggests the
negligible contribution of clastic, minerogenic input from catchment
erosion  and is consistent with the low Ti concentration (e.g. Vogel et al.,
2010). <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">TIC</mml:mi></mml:msub></mml:math></inline-formula> of most Mediterranean lakes is instead
considered a proxy for the balance of precipitation vs. lake evaporation (e.g.
Roberts et al., 2008), with higher or lower values related to decreasing or
increasing moisture conditions, respectively.</p>
      <p>The TOC <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> TN ratio is often related to the source of the OM  and generally
reflects the proportion of aquatic (macrophytes and phytoplankton) vs.
terrestrial plants, with higher values indicating prevailing allochthon
(terrestrial) input for the OM (Meyers and Ishiwatari, 1995), i.e. enhanced
development of vegetation in the lake catchment. However, some sections in
the core indicate TOC <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> TN ratios as low as <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 2 (Fig. 5). As
this is too low for natural substances, selective decomposition of OM could
have taken place and may have affected the TOC <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> TN ratio. In addition, very
low amounts of TOC or TN, which are close to the detection limits, may have
biased the TOC <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> TN ratio. TS is related to variations in OM production and in
redox conditions within the lake. In our record, the high positive
correlation between TS and TOC (<inline-formula><mml:math display="inline"><mml:mrow><mml:mi>r</mml:mi><mml:mo>=</mml:mo><mml:mn>0.70</mml:mn></mml:mrow></mml:math></inline-formula>) and their similar patterns suggest
that higher S values are related to the development of anoxic conditions at the
bottom of the lake due to increasing productivity and/or lake stratification.</p>
      <p>Based on their paleoclimatic/paleoenvironmental significance, the consistent
variations in all of the presented proxies (Fig. 5) perfectly match the
timescale proposed by the preliminary tephrochronological framework (Fig. 4).
Indeed, lower precipitation (higher <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mi mathvariant="normal">TIC</mml:mi></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>,  reduced
lake productivity (lower TIC, TOC, and TS), contraction of terrestrial
vegetation (lower TOC <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> TN ratio), and increase in catchment erosion (higher
Ti) correspond  to the colder glacial conditions of the MIS 6 and MIS 4–2
(Fig. 5). During the glacial part of the MIS 5 and the interglacial MIS 5.5
and MIS 1, warmer and wetter climate conditions, promoting primary
productivity and vegetation development, are instead apparent.
Interestingly, although the temporal resolution of the proxy obtained from
the core catcher (<inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O, TIC, TOC, TOC <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> CN, and TS) is very low
(<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 2 ka, based on the preliminary estimation of the
sedimentation rate of ca. 0.45 mm a<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>)  the interstadial/stadial pattern
during the MIS 5 is also recorded by concurrent variations in all the
investigated proxies (Fig. 5). This notion is corroborated also by the
similarities of the Fucino record with the high-resolution oxygen isotope
time series from the Sulmona Basin (Regattieri et al., 2015, Fig. 4).
Indeed, although the two series are correlated only by means of the
preliminary tephrostratigraphic analyses (Fig. 4), across the four
presumably common tephras, the F1–3 <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">TIC</mml:mi></mml:msub></mml:math></inline-formula> profile seems
to show the same pronounced millennial-scale fluctuations documented in
the Sulmona record (Fig. 4).</p>
</sec>
<sec id="Ch1.S5" sec-type="conclusions">
  <title>Conclusions</title>
      <p>The first multiproxy analyses performed on the newly acquired 82 m long core
from Fucino lake sediments, along with the reinterpretation of the previous
data, suggest that
<list list-type="custom"><list-item><label>i.</label><p>the entire lacustrine succession in the Fucino Basin extends continuously at
least up to <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 540 ka and, by extrapolating the sedimentation
rate (0.4–0.5  mm a<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>) to the maximum depth of ca. 900 m, possibly 2 Ma back ;</p></list-item><list-item><label>ii.</label><p>the Fucino sediments include several tephra layers from the surrounding
peri-Tyrrhenian volcanic centres, most of which are suitable for both
indirect (geochemical fingerprinting) and direct (<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mn>40</mml:mn></mml:msup></mml:math></inline-formula>Ar/<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mn>39</mml:mn></mml:msup></mml:math></inline-formula>Ar)
dating;</p></list-item><list-item><label>iii.</label><p>the geochemical and biogeochemical properties alongside the pollen record
suggest a high sensitivity of the Fucino lacustrine sediments to the
climatic and environmental changes.</p></list-item></list></p>
      <p>In order to explore the full potential of the Fucino succession, further
investigations, including detailed tephra analyses, <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mn>14</mml:mn></mml:msup></mml:math></inline-formula>C and
<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mn>40</mml:mn></mml:msup></mml:math></inline-formula>Ar/<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mn>39</mml:mn></mml:msup></mml:math></inline-formula>Ar geochronology, and high-resolution biogeochemical,
stable isotope, paleontological, and paleomagnetic analyses  are in progress.
Nevertheless, the present preliminary results make the Fucino Basin a good
candidate for a deep-drilling project, which could provide one of the
longest continuous records for studying, at both orbital and millennial
scale, the Quaternary paleoclimatic history of the central Mediterranean
area, possibly  2 Ma back.</p>
</sec>

      
      </body>
    <back><ack><title>Acknowledgements</title><p>We thank  Michele and Valentino Pietrantoni for having kindly hosted us and
for having permitted to perform the drilling in their farm. Alison Pereira
is thanked for field help during the drilling. Alex Francke and Niklas Leicher
provided valuable help during core management at the University of Koln.<?xmltex \hack{\newline}?><?xmltex \hack{\newline}?>
Edited by: U. Harms<?xmltex \hack{\newline}?>
Reviewed by: J. Brigham-Grette and one anonymous referee</p></ack><?xmltex \hack{\newpage}?><?xmltex \hack{\newpage}?><ref-list>
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  </ref-list><app-group content-type="float"><app><title/>

    </app></app-group></back>
    <!--<article-title-html>A key continental archive for the last 2 Ma of climatic
history of the central Mediterranean region: A pilot drilling in the Fucino Basin, central Italy</article-title-html>
<abstract-html><h6 xmlns="http://www.w3.org/1999/xhtml" xmlns:m="http://www.w3.org/1998/Math/MathML" xmlns:svg="http://www.w3.org/2000/svg">Abstract. </h6><p xmlns="http://www.w3.org/1999/xhtml" xmlns:m="http://www.w3.org/1998/Math/MathML" xmlns:svg="http://www.w3.org/2000/svg" class="p">An 82 m long sedimentary succession was retrieved from the Fucino Basin, the
largest intermountain tectonic depression of the central Apennines. The basin
hosts a succession of fine-grained lacustrine sediments (ca. 900 m-thick)
possibly continuously spanning the last 2 Ma. A preliminary
tephrostratigraphy study allows us to ascribe the drilled 82 m long record
to the last 180 ka. Multi-proxy geochemical analyses (XRF scanning, total
organic/inorganic carbon, nitrogen and sulfur, oxygen isotopes) reveal
noticeable variations, which are interpreted as paleohydrological and
paleoenvironmental expressions related to classical glacial–interglacial
cycles from the marine isotope stage (MIS) 6 to present day. In light of the
preliminary results, the Fucino sedimentary succession is likely to provide
a long, continuous, sensitive, and independently dated paleoclimatic archive
of the central Mediterranean area.</p></abstract-html>
<ref-html id="bib1.bib1"><label>1</label><mixed-citation>
Cavinato, G. P., Carusi, C., Dall'Asta, M., Miccadei, E., and Piacentini, T.:
Sedimentary and tectonic evolution of Plio–Pleistocene alluvial and
lacustrine deposits of Fucino Basin (central Italy), Sediment. Geol.,
148, 29–59, 2002.
</mixed-citation></ref-html>
<ref-html id="bib1.bib2"><label>2</label><mixed-citation>
D'Agostino, N., Jackson, J. A., Dramis, F., and Funiciello, R.: Interactions
between mantle upwelling, drainage evolution and active normal faulting: an
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