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<article xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:oasis="http://docs.oasis-open.org/ns/oasis-exchange/table" xml:lang="en" dtd-version="3.0"><?xmltex \bartext{Progress Reports}?>
  <front>
    <journal-meta><journal-id journal-id-type="publisher">SD</journal-id><journal-title-group>
    <journal-title>Scientific Drilling</journal-title>
    <abbrev-journal-title abbrev-type="publisher">SD</abbrev-journal-title><abbrev-journal-title abbrev-type="nlm-ta">Sci. Dril.</abbrev-journal-title>
  </journal-title-group><issn pub-type="epub">1816-3459</issn><publisher>
    <publisher-name>Copernicus Publications</publisher-name>
    <publisher-loc>Göttingen, Germany</publisher-loc>
  </publisher></journal-meta>
    <article-meta>
      <article-id pub-id-type="doi">10.5194/sd-26-17-2019</article-id><title-group><article-title>Coring the sedimentary expression of the early Toarcian Oceanic Anoxic
Event: new stratigraphic records from the Tethys Ocean</article-title><alt-title>Coring the sedimentary expression of the early Toarcian Oceanic Anoxic Event</alt-title>
      </title-group><?xmltex \runningtitle{Coring the sedimentary expression of the early Toarcian Oceanic Anoxic Event}?><?xmltex \runningauthor{E. Erba et al.}?>
      <contrib-group>
        <contrib contrib-type="author" corresp="yes">
          <name><surname>Erba</surname><given-names>Elisabetta</given-names></name>
          <email>elisabetta.erba@unimi.it</email>
        <ext-link>https://orcid.org/0000-0001-6213-6550</ext-link></contrib>
        <contrib contrib-type="author" corresp="no">
          <name><surname>Gambacorta</surname><given-names>Gabriele</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no">
          <name><surname>Visentin</surname><given-names>Stefano</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no">
          <name><surname>Cavalheiro</surname><given-names>Liyenne</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no">
          <name><surname>Reolon</surname><given-names>Dario</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no">
          <name><surname>Faucher</surname><given-names>Giulia</given-names></name>
          
        <ext-link>https://orcid.org/0000-0001-8930-477X</ext-link></contrib>
        <contrib contrib-type="author" corresp="no">
          <name><surname>Pegoraro</surname><given-names>Matteo</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-6141-9070</ext-link></contrib>
        <aff id="aff1"><institution>Dipartimento di Science della Terra, Università degli Studi di
Milano, Milano, Italy</institution>
        </aff>
      </contrib-group>
      <author-notes><corresp id="corr1">Elisabetta Erba (elisabetta.erba@unimi.it)</corresp></author-notes><pub-date><day>2</day><month>December</month><year>2019</year></pub-date>
      
      <volume>26</volume>
      <fpage>17</fpage><lpage>27</lpage>
      <history>
        <date date-type="received"><day>14</day><month>June</month><year>2019</year></date>
           <date date-type="rev-recd"><day>2</day><month>September</month><year>2019</year></date>
           <date date-type="accepted"><day>4</day><month>September</month><year>2019</year></date>
      </history>
      <permissions>
        <copyright-statement>Copyright: © 2019 Elisabetta Erba et al.</copyright-statement>
        <copyright-year>2019</copyright-year>
      <license license-type="open-access"><license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri" xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p></license></permissions><self-uri xlink:href="https://sd.copernicus.org/articles/26/17/2019/sd-26-17-2019.html">This article is available from https://sd.copernicus.org/articles/26/17/2019/sd-26-17-2019.html</self-uri><self-uri xlink:href="https://sd.copernicus.org/articles/26/17/2019/sd-26-17-2019.pdf">The full text article is available as a PDF file from https://sd.copernicus.org/articles/26/17/2019/sd-26-17-2019.pdf</self-uri>
      <abstract><title>Abstract</title>
    <p id="d1e128">The Toarcian Oceanic Anoxic Event (T-OAE) interval was cored at Colle di
Sogno and Gajum in the Lombardy Basin (Southern Alps, northern Italy). The
Sogno and Gajum cores recovered 26.83 and 31.18 stratigraphic metres, respectively, of pelagic sediments consisting of marly
limestones, marlstone, marly claystone, and black shale. Drilling at both
sites resulted in 100 % recovery of unweathered material. The pelagic
succession comprises a relatively expanded black shale interval of 4.98 m in
the Sogno core and 15.35 m in the Gajum core, with lower and upper
boundaries without evidence of hiatuses. The Sogno and Gajum cores can be
considered reference sections for the pelagic lower Toarcian interval of the
western Tethys and will provide high-resolution micropaleontological,
inorganic and organic geochemical, isotopic multiproxy data. Integrated
stratigraphy and cyclostratigraphy are predicted to result in estimates of
durations and rates to model the ecosystem resilience to the extreme
perturbations of the T-OAE and gain a better understanding of current global
changes and help provide better projections of future scenarios.</p>
  </abstract>
    </article-meta>
  </front>
<body>
      

<sec id="Ch1.S1" sec-type="intro">
  <label>1</label><title>Introduction</title>
      <p id="d1e140">The emergence of climate change as a crucial issue for society has urged the
understanding of the future state of the planet within the context of
increasing carbon dioxide concentrations. The ocean is the oldest ecosystem and the largest on Earth by volume and best records global changes in
climate and atmospheric composition. Marine ecosystems are inextricably
involved in the physical, chemical, biological processes of global change.
In the near future, the ocean's uptake of <inline-formula><mml:math id="M1" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> is expected to rapidly
decline because of surface water warming, decreasing pH (acidification),
increased vertical stratification, and slowed thermohaline circulation
(Solomon et al., 2009). Consequently, a very rapid “in and out” from
icehouse to greenhouse state – and vice versa – urges comprehension of positive and
negative feedbacks on the biosphere.</p>
      <p id="d1e154">Understanding of the Earth system at timescales longer than human
observations has became imperative, because anthropogenic activities are
likely to increase by orders of magnitude the rates of climatic change that
usually result from natural processes. The Earth's ecosystems, thus, should
be scrutinized on the medium- and long-term scales using geological records of past extreme environmental disturbances that exemplify varied tempos and
modes of resilience, occasionally reaching tipping points that triggered
permanent modifications.</p>
      <p id="d1e157">The Toarcian Oceanic Anoxic Event (T-OAE) is the oldest Mesozoic case of
global anoxia with widespread deposition of organic matter-rich sediments in
a variety of depositional settings from continental to shallow- and
deep-marine (Jenkyns, 1985, 1988, 2010). Available evidence
suggests that at <inline-formula><mml:math id="M2" display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">183</mml:mn></mml:mrow></mml:math></inline-formula> Ma the atmosphere and oceans experienced
high <inline-formula><mml:math id="M3" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, possibly due to the degassing of lava fields in the Karoo–Ferrar
large igneous province and/or from dissociation and oxidation of methane
hydrates in continental-margin sediments (Jenkyns, 2010) and/or terrestrial
environments (Them et al., 2017). High atmospheric carbon dioxide possibly
initiated greenhouse conditions that accelerated<?pagebreak page18?> weathering and the
hydrological cycle, increasing nutrient recycling into the oceans.</p>
      <p id="d1e181">Although the original definition of the T-OAE was based on the presence of a
lithostratigraphic marker (Jenkyns, 1985), the development of
chemostratigraphy demonstrated that the T-OAE is associated with a negative
C isotopic anomaly documented in marine carbonates and organic matter as
well as in terrestrial organic matter including fossil wood and specific
organic compounds (Jenkyns and Clayton, 1986; Hesselbo et al., 2000, 2007;
Schouten et al., 2000; Jenkyns et al., 2002; Emmanuel et al., 2006; Van
Breugel et al., 2006; Al-Suwaidi et al., 2010; Caruthers et al., 2011; Izumi
et al., 2012; Kafousia et al., 2014; Reolid, 2014; Xu et al., 2017; Them et
al., 2017; Fantasia et al., 2018). As shown by Fantasia et al. (2018),
such a negative C isotopic anomaly might have resulted from volcanogenic
<inline-formula><mml:math id="M4" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, thermogenic methane associated with metamorphism, and dissociation
of marine or terrestrial clathrates.</p>
      <p id="d1e196">The T-OAE is further marked by an Os anomaly (Cohen et al., 2004; Percival et
al., 2016; Them et al., 2017), biocalcification crisis (Erba, 2004; Mattioli
et al., 2004; Casellato and Erba, 2015; Erba et al., 2019), increased
primary productivity (Jenkyns, 2010; Erba, 2004), and ocean acidification
(Erba, 2004; Trecalli et al., 2012; Casellato and Erba, 2015; Posenato et
al., 2018), which occurred during an exceptional warming phase (Dera et al.,
2011; Korte and Hesselbo, 2011; Gómez et al., 2016) and a major
transgression (e.g. Haq et al., 1987; Hardenbol et al., 1998).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F1" specific-use="star"><?xmltex \currentcnt{1}?><label>Figure 1</label><caption><p id="d1e201">Location of the Sogno and Gajum drilling sites relative to <bold>(a)</bold> paleogeography and <bold>(b)</bold> current geography. The drilling area was part of the Lombardy
Basin (Southern Alps). <bold>(c)</bold> The Gajum core is sited in an inner basin along
the western slope of the Corni di Canzo High while <bold>(d)</bold> the Sogno core was
drilled on the Albenza Plateau as detailed in the geological sections in the
lower part of the figure (modified after Gaetani and Poliani, 1978 and
Gaetani and Erba, 1990).</p></caption>
        <?xmltex \igopts{width=497.923228pt}?><graphic xlink:href="https://sd.copernicus.org/articles/26/17/2019/sd-26-17-2019-f01.png"/>

      </fig>

      <p id="d1e222">Jurassic pelagic successions in the Southern Alps have been extensively
investigated for stratigraphy, sedimentology, paleontology, and geochemistry
(Bernoulli and Jenkyns, 2009; Erba et al., 2019). In particular, multi- and
interdisciplinary studies have demonstrated that the Jurassic pelagic
successions of the Lombardy Basin represent “type-sections” of the Tethyan
southern margin (Gaetani, 2010). Indeed, the Lombardy Basin is part of the
relatively undeformed portion of Adria interpreted as an African
“promontory” or as a microplate (Fig. 1). In the latest Triassic–earliest
Jurassic a rifting phase caused the breakup of carbonate platforms into a
series of “horst and graben” that exerted a physiographic control on
sediment type and distribution for most of the Jurassic (Bernoulli and
Jenkyns, 1974, 2009; Bosence et al., 2009; Santantonio and Carminati, 2011).
As a consequence, sedimentation was differentiated with the deposition of
thick complete pelagic successions in the deeper zones, while sedimentation
was typically condensed and incomplete on the structural
highs.</p>
      <p id="d1e225">During the Jurassic the Lombardy Basin was globally a deep area between the
Lugano High to the west and the Trento Plateau to the east (Fig. 1).
However, the latest Triassic–earliest Jurassic rifting disentangled a number
of troughs and paleohighs that are as follows, from west to east: Monte Nudo Trough,
Lugano High, Generoso Trough, Corni di Canzo High, Albenza Plateau, Monte
Cavallo High, Sebino Trough, Botticino High (Gaetani, 1975, 2010). In the
troughs, partially resedimented Lower Jurassic marlstone–limestone sequences
may reach a non-decompacted thickness of 3000 m (e.g. in the Generoso
Trough), but condensation and hiatuses characterize the paleohigh sections
with reddish nodular facies. Along slopes connecting structural highs to the
troughs, sedimentation was marked by slumps, resedimented bodies, and,
locally, megabreccias within condensed and occasionally incomplete facies
(Gaetani and Erba, 1990; Gaetani, 2010) (Fig. 1). In addition to regional
tectonics, the Lombardy Basin successions record global climatic and
oceanographic changes, including the T-OAE (Erba et al., 2019). In fact,
lower Toarcian black shales have been documented in various sections,
offering the opportunity to investigate the consequences of the T-OAE global
changes on marine biota in the Tethys Ocean (Erba et al., 2019).</p>
      <p id="d1e228">After close investigations of section outcropping in the Lombardy Basin,
the Colle di Sogno and Gajum sites were selected as the most promising locations
for continuous coring of pelagic records (Gaetani and Erba, 1990; Casellato
and Erba, 2015) for continuous coring. In this paper, we document coring
operations and lithostratigraphic characterization of both the Sogno and
Gajum cores and outline ongoing multidisciplinary research.</p>
</sec>
<sec id="Ch1.S2">
  <label>2</label><title>Coring through the sedimentary record of the early Toarcian Oceanic Anoxic Event</title>
      <p id="d1e239">The T-OAE is considered a natural Earth system experiment, which allows us
to (a) detect and quantify processes associated with emissions of
greenhouse gases and natural atmospheric pollutants; (b) understand the role
of greenhouse gases on climate dynamics and its influence on the
hydrological cycle; (c) characterize changes in ocean and atmospheric
chemistry and their interactions; (d) assess changes in biodiversity and
dynamics of ecosystems and understand the functioning of biotic sinks; and (e) quantify biosphere–geosphere–atmosphere interactions and their
timings or rates.</p>
      <p id="d1e242">Analysis of past global change requires the collection of high-resolution
data from continuous and ideally unweathered sequences. In surface outcrops,
sedimentary rocks and particularly black shales are commonly badly degraded
and, consequently, drilling is crucial to ensure the recovery of
high-quality fresh cored material. In this paper we identify the T-OAE
adopting the original definition by Jenkyns (1985) based on
lithostratigraphy. Therefore, the T-OAE in the Lombardy Basin corresponds to
the Livello a Pesci (Tintori, 1977; Gaetani and Poliani, 1978; Erba and
Casellato, 2010; Erba et al., 2019). This interval has an average thickness
of 0.5 to 5 m, but reaches a few tens of metres in the most expanded
sections. Black shales are rarely recorded on paleohighs, whereas they are
ubiquitous in deeper basins. As the T-OAE occurred at a global scale, the
local lack of black shales<?pagebreak page19?> in the Lombardy Basin is usually the result of
condensation and/or stratigraphic gaps.</p>
<sec id="Ch1.S2.SSx1" specific-use="unnumbered">
  <title>Location of the drill sites and justification for coring</title>
      <p id="d1e250">Two Lower Jurassic sections at Colle di Sogno and Gajum, respectively, were
selected for continuous coring through the Toarcian organic-rich black shale
interval (Fig. 1). Within the Lombardy Basin, these sections represent
significantly different geological settings on a pelagic structural high,
namely the Albenza Plateau (Colle di Sogno) and in an inner basin along the
slope of the Mt Corni di Canzo structural high (Gajum) (Gaetani and Erba,
1990; Gaetani, 2010). Both successions are relatively expanded and lack the
diagenetic manganese–carbonate horizons (present in the Toarcian black
shales of the Belluno Basin, Southern Alps, for example) that would
compromise primary geochemical signatures (Farrimond et al., 1988; Jenkyns,
1988; Jenkyns et al., 1991; Bellanca et al., 1999).</p>
      <p id="d1e253">The Colle di Sogno site (Fig. 1) was selected because the Jurassic sequence
exposed is pelagic, stratigraphically continuous and relatively expanded
(Gaetani and Erba, 1990; Muttoni et al., 2005; Channell et al., 2010;
Casellato and Erba, 2015). It consists of limestone and marlstone, with chert
and marly claystone as minor lithologies. The T-OAE is here represented by
<inline-formula><mml:math id="M5" display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">5</mml:mn></mml:mrow></mml:math></inline-formula> m of dark grey to black marly claystones of the
Livello a Pesci. At Colle di Sogno, the type-section of the Sogno Formation
(Gaetani and Poliani, 1978), located along the road SP 179 on the northern
slope of Mt Brughetto, was proved to be suitable for high-resolution
multidisciplinary studies of litho-, bio-, chemo-, magneto-, and
cyclo-stratigraphy (Gaetani and Poliani, 1978; Jenkyns and Clayton, 1986;
Gaetani and Erba, 1990; Hinnov et al., 2000; Channell et al., 2010;
Casellato and Erba, 2015).</p>
      <?pagebreak page20?><p id="d1e266">The Gajum succession crops out in a small lateral cut of the Ravella valley
(Fig. 1), where the basal lithofacies of the Moltrasio Limestone Formation
suggests sedimentation in shallower water than on the Albenza Plateau
(Gaetani and Poliani, 1978; Gaetani and Erba, 1990; Pasquini and Vercesi,
2002). In particular, slumps and resedimented bodies with an
eastward-sliding direction document a constant instability of the ramp,
indicating that the succession developed in a small inner basin separated by
a sill from a deeper basin to the west (Pasquini and Vercesi, 2002). A sharp
lithological change marks the boundary between the carbonate-rich
lithologies of the Domaro Limestone Formation and the overlying clay-rich
lithologies of the lower Sogno Formation consisting of marlstones and marly
limestones followed by reddish nodular limestones of the Rosso Ammonitico
Lombardo. At Gajum the expanded nature of the black shale interval
(<inline-formula><mml:math id="M6" display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">15</mml:mn></mml:mrow></mml:math></inline-formula> m) offers the opportunity for studying the
inception, evolution, and termination of the T-OAE in great detail.</p>
</sec>
</sec>
<sec id="Ch1.S3">
  <label>3</label><title>Drilling operations and lab core preparation</title>
      <p id="d1e288">The Sogno drilling campaign took place in June 2013, while the Gajum core
was drilled in February 2016 (Fig. 2). At both Sogno and Gajum sites,
drilling operations were performed with the DELTABASE 520 Modular Hydraulic
Rotary Drill. The Sogno coring was accomplished with a T2 double corer,
using narrow-kerf, sawtoothed drill bits that cut a 101 mm diameter borehole
and 84 mm diameter cores. The Gajum core was obtained using a modified T6
triplex corer, including a plastic liner for the best recovery, using
narrow-kerf, sawtoothed drill bits that cut a 131 mm diameter borehole and
101 mm diameter cores. At Gajum, after coring, the borehole was logged using
a QL40-OBI optical televiewer to obtain high-resolution images of the
borehole wall, together with a total gamma radiation tool (Fig. 3).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F2" specific-use="star"><?xmltex \currentcnt{2}?><label>Figure 2</label><caption><p id="d1e293">Coring operations and results at Sogno and Gajum sites. <bold>(a)</bold> Coring
Sogno Site 4. <bold>(b)</bold> Livello a Pesci in the Sogno core compared to the
equivalent outcropping lithostratigraphic interval. <bold>(c)</bold> Coring at Gajum. <bold>(d)</bold> Black shale interval recovered in core 10 of the Gajum core.</p></caption>
        <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://sd.copernicus.org/articles/26/17/2019/sd-26-17-2019-f02.jpg"/>

      </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F3" specific-use="star"><?xmltex \currentcnt{3}?><label>Figure 3</label><caption><p id="d1e316">Example of Gajum borehole wall image recorded with a QL40-OBI
optical televiewer. From left to right: borehole depth, 360<inline-formula><mml:math id="M7" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>
continuous upwrapped digital image of the borehole wall, total natural gamma
ray, 3-D log visualization reproducing a virtual core of the borehole.</p></caption>
        <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://sd.copernicus.org/articles/26/17/2019/sd-26-17-2019-f03.png"/>

      </fig>

      <p id="d1e335">All cores were initially described on site and a preliminary log was
produced. Then, cores were packed, labelled, and put in PVC plastic boxes to
prevent contamination and transported to the Department of Earth Sciences in
Milan where they are archived. Here, during lab preparation, all cores were
longitudinally split along the dip and divided into an archive half and a sampling half, both marked at centimetre scale. The archive half was photographed in high resolution and composite photologs were produced for each site.</p>
</sec>
<sec id="Ch1.S4">
  <label>4</label><title>Preliminary results</title>
<sec id="Ch1.S4.SS1">
  <label>4.1</label><title>Lithostratigraphy of the Sogno core</title>
      <p id="d1e353">Four distinct boreholes (S1, S2, S3, and S4) were drilled at Colle di Sogno
along the SP 179 road (45<inline-formula><mml:math id="M8" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>47<inline-formula><mml:math id="M9" display="inline"><mml:msup><mml:mi/><mml:mo>′</mml:mo></mml:msup></mml:math></inline-formula>20.5<inline-formula><mml:math id="M10" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>′</mml:mo><mml:mo>′</mml:mo></mml:mrow></mml:msup></mml:math></inline-formula> N, 9<inline-formula><mml:math id="M11" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>28<inline-formula><mml:math id="M12" display="inline"><mml:msup><mml:mi/><mml:mo>′</mml:mo></mml:msup></mml:math></inline-formula>30.0<inline-formula><mml:math id="M13" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>′</mml:mo><mml:mo>′</mml:mo></mml:mrow></mml:msup></mml:math></inline-formula> E).
The outcropping beds show a strike of 150<inline-formula><mml:math id="M14" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> and a dip of
68<inline-formula><mml:math id="M15" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> to the southwest (240<inline-formula><mml:math id="M16" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F4" specific-use="star"><?xmltex \currentcnt{4}?><label>Figure 4</label><caption><p id="d1e446">Section and plan view of the relative positions of the four
boreholes drilled at Colle di Sogno. A pronounced fold was encountered at
<inline-formula><mml:math id="M17" display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">25</mml:mn></mml:mrow></mml:math></inline-formula> m penetration depth in Sogno borehole 1 that was
abandoned after reaching the topmost part of the black shale interval. Three
additional boreholes were cored as explained in the text.</p></caption>
          <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://sd.copernicus.org/articles/26/17/2019/sd-26-17-2019-f04.png"/>

        </fig>

      <p id="d1e465">Initially, a single borehole was planned to penetrate the lower
Toarcian–uppermost Pliensbachian interval and reach the base of the Sogno Formation
at <inline-formula><mml:math id="M18" display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">35</mml:mn></mml:mrow></mml:math></inline-formula> m penetration depth. However, at <inline-formula><mml:math id="M19" display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">25</mml:mn></mml:mrow></mml:math></inline-formula> m
penetration depth (core S1-27) a sharp dip increase to 88<inline-formula><mml:math id="M20" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>
revealed the occurrence of a fold, partially faulted and reversed,
persisting for <inline-formula><mml:math id="M21" display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">4</mml:mn></mml:mrow></mml:math></inline-formula> m (cores S1-27, S1-28, and S1-29).
Indeed, core S1-30 perfectly correlates with the lower part of core S1-26
and two black shales were used as lithostratigraphic markers. Coring was
extended for <inline-formula><mml:math id="M22" display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:math></inline-formula> m (cores S1-31 and S1-32) penetrating
the top of the black shale interval and then operations were interrupted to
shift drilling to borehole S2 (Fig. 4). Due to the steep dip, it was decided to
perform a 10<inline-formula><mml:math id="M23" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> inclined coring to decrease the total penetration
depth down into the Domaro Limestone Formation. Borehole S2 started just
above the top of the black shale interval of the Livello a Pesci, perfectly
duplicating core S1-32. However, technical problems prevented coring below a
few metres and operations stopped after recovery of core S2-3. The third
borehole (S3) was moved 0.5 m relative to S2 and was cored vertically.
Again, the recovered succession started from just above the top of the black
shale interval with core S3-1 triplicating cores S1-32 and S2-1. Coring was
extended to 40 m penetration depth, reaching the uppermost part of the
Domaro Limestone Formation (Fig. 4). A fourth borehole (S4) was performed to
duplicate the middle and lower portion of the black shale interval to ensure
material for multidisciplinary investigations. The recovery percentage for
the four boreholes is 99.9 %.</p>

      <?xmltex \floatpos{p}?><fig id="Ch1.F5" specific-use="star"><?xmltex \currentcnt{5}?><label>Figure 5</label><caption><p id="d1e530">Lithostratigraphy and calcium carbonate content of the Sogno
<bold>(a)</bold> and Gajum <bold>(b)</bold>   cores. The grey pattern highlights the Livello a
Pesci black shale interval that is the lithostratigraphic record of the T-OAE
in the Lombardy Basin. The <inline-formula><mml:math id="M24" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CaCO</mml:mi><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> content was detected using the
Dietrich-Frühling gas volumetric method by measuring
evolved <inline-formula><mml:math id="M25" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> after acidification of the bulk sample with HCl.</p></caption>
          <?xmltex \igopts{width=412.564961pt}?><graphic xlink:href="https://sd.copernicus.org/articles/26/17/2019/sd-26-17-2019-f05.png"/>

        </fig>

      <p id="d1e567">Lithostratigraphic units were defined on the basis of lithological features
(i.e. lithology and colours determined with the Munsell Rock Color Chart) and
sedimentary structures (i.e. presence or lack of bioturbation and/or
lamination). For each core at least four dip measurements were taken during
lab preparation to calculate the stratigraphic thickness of the drilled
section as 25.33 m under 1.5 m of rubble at the top. A complete composite
section, representing the upper Pliensbachian–lower Toarcian interval, was
created by combining the data obtained from the S1 and S3 boreholes (Fig. 5).
The following key observations were derived:
<list list-type="order"><list-item>
      <p id="d1e572">The first 1.5 m of the S1 borehole are represented by soil cover and
rubble.</p></list-item><list-item>
      <p id="d1e576">The S1 core, despite the occurrence of a faulted fold disturbing the
succession, recovered a complete section above the Livello a Pesci. The
bottommost part of the well reached the uppermost part of the black shale
interval. This correlates with the top black shale interval recovered in
the upper part of the S3 core.</p></list-item><list-item>
      <p id="d1e580">The upper limit of the black shale interval was cored both at S1 and S3
sites.</p></list-item><list-item>
      <p id="d1e584">The S3 core recovered a few metres of succession above the black shale interval, the entire Livello a Pesci, and the lower portion of the Sogno
Formation, in addition to the topmost part of the Domaro Limestone. In
particular, at 25.47 m, the lithostratigraphic boundary between<?pagebreak page21?> the
Sogno Formation and Domaro Limestone Formation was recovered.</p></list-item></list></p>
      <p id="d1e587">Combining the above information and considering the dip measured in
individual cores (variable in the range of 60 to 87<inline-formula><mml:math id="M26" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>),
the “stratigraphic thickness” of each lithostratigraphic unit was
calculated. The overlapping intervals (i.e. U1-5 and U3-1) were matched and
duplications were eliminated. The lithologic log of the composite S1–S3
Sogno core, in stratigraphic depths (from 1.5 to 26.83 m), is
illustrated in Fig. 5. The composite S1–S3 Sogno core section recovered a
complete upper Pliensbachian–lower Toarcian interval, with the S1 core
representing its upper portion, and the S3 core the lower part.</p>
      <p id="d1e599">The following lithostratigraphic units (U1-1 to U1-5, and U3-2 to U3-11, of
the S1 and S3 cores, respectively) are described, from the topmost to the
bottommost:
<list list-type="bullet"><list-item>
      <p id="d1e604"><italic>Unit 1 (1.50 to 4.82 m): marly limestones, olive-grey in colour</italic>. In the upper
and lowermost parts of the unit, high concentrations of reddish mottles and
sporadic bioturbation are documented.</p></list-item><list-item>
      <p id="d1e610"><italic>Unit 2 (4.82 to 9.54 m): marly limestones, olive-grey in colour, characterized by intense bioturbation</italic>. In particular, the uppermost part of the unit
documents the presence of frequent <italic>Planolites</italic>.</p></list-item><list-item>
      <p id="d1e619"><italic>Unit 3 (9.54 to 10.52 m): marly limestones, grey in colour, characterized by intense bioturbation</italic>. Locally, faintly laminated intervals are observed.</p></list-item><list-item>
      <p id="d1e625"><italic>Unit 4 (10.52 to 11.87 m): marly limestones with evident and widespread bioturbation</italic>. Locally, 1 to 6 cm thick black shales and laminated intervals are
present.</p></list-item><list-item>
      <p id="d1e631"><italic>Unit 5 (11.87 to 14.55 m): black shales characterized by well-developed lamination, especially in the uppermost part, in addition to pyrite nodules</italic>.
In the lower portion, very little bioturbation is documented.</p></list-item><list-item>
      <p id="d1e637"><italic>Unit 6 (14.55 to 15.93 m): marly limestones, grey to very dark-grey in colour, with reddish to greyish spots</italic>. Bioturbation (burrow) dimensions increase
within this unit and thin emerald-green laminae are documented.</p></list-item><list-item>
      <p id="d1e643"><italic>Unit 7 (15.93 to 16.86 m): marly limestones, with variations in colour from grey, to very dark-grey and dark-red</italic>. In the lowermost portion, bioturbation
and lamination are observed.</p></list-item><list-item>
      <p id="d1e649"><italic>Unit 8 (16.86 to 19.10 m): marly limestones, dark-red in colour, with sporadic greyish spots</italic>.</p></list-item><list-item>
      <p id="d1e655"><italic>Unit 9 (19.10 to 19.45 m): marly limestones, grey in colour</italic>.</p></list-item><list-item>
      <p id="d1e661"><italic>Unit 10 (19.45 to 21.35 m): marly limestones, grey-brown in colour</italic>. This is a
disturbed interval comprising a level of pebbly marlstones (between 19.45
and 20.03 m), with minor slump structures. Sporadic stylolites are present.</p></list-item><list-item>
      <p id="d1e667"><italic>Unit 11 (21.35 to 22.92 m): marly limestones, grey in colour, characterized by frequent stylolite structures</italic>. In addition, 2 cm thick black shale
intervals are documented at <inline-formula><mml:math id="M27" display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">21.8</mml:mn></mml:mrow></mml:math></inline-formula> and 22 m,
respectively.</p></list-item><list-item>
      <p id="d1e684"><italic>Unit 12 (22.92 to 24.35 m): marly limestones, alternating in colour from reddish to olive-grey</italic>. Sporadic bioturbation and lamination can be observed.</p></list-item><list-item>
      <p id="d1e690"><italic>Unit 13 (24.35 to 24.99 m): marly limestones, reddish-greyish in colour</italic>.</p>
      <p id="d1e695"><italic>Unit 14 (24.99 to 25.47 m): marly limestones, light-brown to grey-brown in colour</italic>. Small and large (1 cm thick) burrows are documented. The base of this
unit corresponds to the base of the Sogno Formation.</p></list-item><list-item>
      <p id="d1e701"><italic>Unit 15 (25.47 to 26.83 m): marly limestones, olive-grey to dark-grey in colour</italic>. Small bioturbations and frequent stylolite structures are observed.
This unit corresponds to the uppermost part of the Domaro Limestone
Formation.</p></list-item></list></p>
</sec>
<?pagebreak page22?><sec id="Ch1.S4.SS2">
  <label>4.2</label><title>Lithostratigraphy of the Gajum core</title>
      <?pagebreak page23?><p id="d1e714">The Gajum core (45<inline-formula><mml:math id="M28" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>51<inline-formula><mml:math id="M29" display="inline"><mml:msup><mml:mi/><mml:mo>′</mml:mo></mml:msup></mml:math></inline-formula>03.2<inline-formula><mml:math id="M30" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>′</mml:mo><mml:mo>′</mml:mo></mml:mrow></mml:msup></mml:math></inline-formula> N, 09<inline-formula><mml:math id="M31" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>17<inline-formula><mml:math id="M32" display="inline"><mml:msup><mml:mi/><mml:mo>′</mml:mo></mml:msup></mml:math></inline-formula>19.5<inline-formula><mml:math id="M33" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>′</mml:mo><mml:mo>′</mml:mo></mml:mrow></mml:msup></mml:math></inline-formula> E, at
555 m above sea level) was drilled close to “Fonte Gajum” – Canzo (CO), in the Ravella
valley next to the trail named Via delle Alpi (Fig. 1). The outcropping beds
show a strike of 245<inline-formula><mml:math id="M34" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> and a dip of 46<inline-formula><mml:math id="M35" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> to the northwest
(335<inline-formula><mml:math id="M36" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>).</p>
      <p id="d1e805">A single borehole was drilled at Gajum to a total penetration depth of 42.37 m, with 100 % recovery of excellent-quality material throughout drilling
operation. For each core a set of dip measurements was taken during lab
preparation, with four measurements on average, and used to calculate the
corrected thickness of the drilled section as 28.18 m after removal of 3 m of rubble at the top. As for the Sogno core, lithostratigraphic units
were defined based on lithological features and sedimentary structures. The
dip measured in individual cores (variable in the range of 40 to
50<inline-formula><mml:math id="M37" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>) was used to calculate the “stratigraphic thickness” of
each lithostratigraphic unit described below, from the topmost to the
bottommost:
<list list-type="bullet"><list-item>
      <p id="d1e819"><italic>Unit 1 (3.00 to 4.35 m): dark brown to dusky red nodular limestone</italic>. nodules
are 3–5 cm in size and light grey in colour. A resedimented level,
consisting of a microbreccia, is detected at 3.92–3.96 m. This unit
corresponds to the lower part of the Rosso Ammonitico Lombardo.</p></list-item><list-item>
      <p id="d1e825"><italic>Unit 2 (4.35 to 7.60 m): marly limestone, grey to olive grey in colour, with dark grey laminated intervals</italic>. Three black shale intervals occur at
5.24–5.35, 6.26–6.43, and 6.70–6.81 m.</p></list-item><list-item>
      <p id="d1e831"><italic>Unit 3 (7.60 to 10.60 m): grey to dark grey marly limestone, with heavily bioturbated levels alternating with intervals characterized by faint lamination</italic>. Some pyrite nodules are observed in the lowermost part of the
unit.</p></list-item><list-item>
      <p id="d1e837"><italic>Unit 4 (10.60 to 21.39 m): dark to very dark grey to black marly claystones</italic>.
This “black shale” interval is characterized by well-developed lamination
and frequent pyrite nodules. In the upper and middle portion, discrete
intervals with faint bioturbation are observed.</p></list-item><list-item>
      <p id="d1e843"><italic>Unit 5 (21.39 to 25.42 m): dark to very dark grey to black marly claystones characterized by well-developed lamination and a few pyrite nodules</italic>. Three
intervals of dusky red limy cherts are identified at 21.39–21.87,
23.52–23.81, and 24.30–25.52 m. The highest and lowest cherty reddish
levels delimit the top and bottom of this unit, respectively.</p></list-item><list-item>
      <p id="d1e849"><italic>Unit 6 (25.42 to 26.95 m): dark grey to very dark grey to black marly claystones, with evident laminations and sporadic faint bioturbations</italic>. The
base is undulated.</p></list-item><list-item>
      <p id="d1e855"><italic>Unit 7 (26.95 to 31.18 m): grey to reddish grey marly limestones, with fractures filled by diagenetic calcite</italic>.</p></list-item></list></p>
      <p id="d1e860">In Fig. 5 the Sogno and Gajum cores are correlated: the T-OAE black shale
interval is represented in both sections, but with significantly different
thicknesses, namely 4.98 m in the Sogno core and 15.35 m in the Gajum core.
The lithostratigraphic onset and termination of the Livello a Pesci black
shale interval, based on the lowest and highest black marly claystones, are
nicely preserved in both cores, without lithologic evidence of hiatus or
disturbance. In the Gajum core the beginning of the anoxic interval is quite
abrupt and represented by the change from a few centimetres thick, grey,
pseudonodular, and heavily bioturbated marly limestone to black shales with
an irregular base mimicking nodularity of the underlying interval: this
lithostratigraphic boundary is very similar to the onset of the early Aptian
OAE1a in the Cismon core (Erba et al., 2010; Fig. 2). The upper boundary is,
conversely, relatively transitional from laminated black shales to dark grey
marly limestones. In the Sogno core, instead, both the base and top of the
black shale interval are sharp.</p>
      <p id="d1e863">The Livello a Pesci is not homogeneous in the Sogno and Gajum cores: in both
records, the lower part is characterized by the occurrence of a few reddish
levels. These are cherty in the Gajum core (Unit 5) and clayey in the Sogno
core (Unit 7). Also, black shales are dominant in the upper part of the
Livello a Pesci in both cores (Unit 4 of the Gajum core and Unit 5 of the
Sogno core).</p>
      <p id="d1e867">As far as the calcium carbonate content is concerned (Fig. 5) in the Sogno
and Gajum cores, the interval below the Livello a Pesci is characterized by
values of around 60 % and 60 %–80 % <inline-formula><mml:math id="M38" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CaCO</mml:mi><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, respectively. A drop in
calcium carbonate content to an average of 20 % is recorded within the black shale interval in both cores, with lowermost values of 5 % (Gajum core) to 10 %
(Sogno core) in the lowermost part. Above the Livello a Pesci, the
calcium carbonate content reverts to 40 %–60 %, with frequent fluctuations.</p>
</sec>
</sec>
<?pagebreak page25?><sec id="Ch1.S5" sec-type="conclusions">
  <label>5</label><title>Future objectives</title>
      <p id="d1e891">The fresh material recovered with the Sogno and Gajum cores provide complete
and relatively expanded pelagic records from the western Tethys Ocean.
Detailed multidisciplinary investigations are in progress to collect
multi-proxy records for building a high-resolution dataset prodromic for
modelling the nature and significance of the T-OAE. The specific objectives are as follows:
<list list-type="order"><list-item>
      <p id="d1e896"><italic>High-resolution integrated stratigraphy</italic>. This is based on nannofossil biostratigraphy, magnetostratigraphy,
chemostratigraphy, and cyclostratigraphy. Milankovitch cycles will be used to
estimate durations of the T-OAE.</p></list-item><list-item>
      <p id="d1e902"><italic>Detailed studies of critical paleoceanographic parameters</italic>. This includes total organic carbon; isotopic anomalies; and major, minor and
trace elements that will be used to assess changes in surface and bottom
water mass characteristics.</p></list-item><list-item>
      <p id="d1e908"><italic>Identification and quantification of the response of the biosphere</italic>. This is based on quantitative and high-resolution investigation of calcareous
phytoplankton assemblages. In particular, we will focus on the relative
timing and possible phase-lag of the response to the overwhelming forcing
function/s. These relationships will be used to model the resilience of the
oceanic biosphere.</p></list-item><list-item>
      <p id="d1e914"><italic>Characterization of the Early Jurassic climate, ocean dynamics, and their response to orbital cyclicity.</italic>. In particular, we plan to decipher local from regional and global changes
across the paleoenvironmental perturbation. Also, the cyclostratigraphy will
allow for the assessment of the influence of eccentricity, obliquity, and precession
cycles before, during, and after the T-OAE.</p></list-item></list></p>
</sec>

      
      </body>
    <back><notes notes-type="dataavailability"><title>Data availability</title>

      <p id="d1e923">The Sogno and Gajum cores are stored at the Department of Earth Sciences “Ardito Desio” of the University of Milan (Italy). Data are publicly accessible upon request.</p>
  </notes><notes notes-type="authorcontribution"><title>Author contributions</title>

      <p id="d1e929">EE conceived and executed the Sogno and Gajum coring. She coordinated the
lab core work and prepared the paper. GG co-supervised the core
description and contributed to the paper. Other co-authors (SV, LC, DR,
GF, MP) contributed to core splitting, archiving, and sampling.</p>
  </notes><notes notes-type="competinginterests"><title>Competing interests</title>

      <p id="d1e935">The authors declare that they have no conflict of interest.</p>
  </notes><ack><title>Acknowledgements</title><p id="d1e941">The T-OAE coring project derived from fieldwork and in-depth discussions
with Maurizio Gaetani on Jurassic stratigraphy of the Lombardy Basin. We
acknowledge the editor Thomas Wiersberg, and the two reviewers Alicia Fantasia and Stephen Hesselbo, who greatly improved the quality of the
paper with their constructive comments.</p></ack><notes notes-type="financialsupport"><title>Financial support</title>

      <p id="d1e946">This research has been supported by the MIUR (MIUR-PRIN2011 grant no. 2010X3PP8J) awarded to Elisabetta Erba.</p>
  </notes><notes notes-type="reviewstatement"><title>Review statement</title>

      <p id="d1e952">This paper was edited by Thomas Wiersberg and reviewed by Stephen Hesselbo and Alicia Fantasia.</p>
  </notes><ref-list>
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